1, 3??Di??n??butylimidazolium tribromide??mediated chemoselective oxidative cyclization of benzothiazoyl carbaimides: A novel approach toward the synthesis of N??bis?? …

…, T Dadmal, U Kosurkar, K Vijay Kumar

Index: Kumbhare, Ravindra M.; Dadmal, Tulshiram; Kosurkar, Umesh; Vijay Kumar Journal of Heterocyclic Chemistry, 2012 , vol. 49, # 2 p. 342 - 348

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Abstract

Abstract 4-(N, N-Dimethylamino) pyridine is found to be an efficient catalyst for the synthesis of benzothiazoyl carbaimide derivatives using 2-aminobenzothiazoles and phenylisothiocyanates, which on treatment with ionic liquid [bbim][Br 3] at 70 C afforded exclusive formation of N-bis-benzothiazole derivatives in good yield. J. Heterocyclic Chem.,(2012).

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