Liebigs Annalen der Chemie

Synthesis of sphingosine relatives, X. Synthesis of (2S, 3R4E)??1??O??(β??D??glucopyranosyl)??N??[30′??(linoleoyloxy) triacontanoyl]??4??icosasphingenine, a new esterified …

K Mori, H Matsuda

Index: Mori, Kenji; Matsuda, Hiroyuki Liebigs Annalen der Chemie, 1991 , # 6 p. 529 - 535

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Abstract

Abstract (2S, 3R, 4E)-1-O-(β-D-Glucopyranosyl)-N-[30′-(linoleoyloxy) triacontanoyl]-4- icosasphingenine (1) was synthesized from D-glucose, L-serine, 15-pentadecanolide, and linoleic acid. The high-field 1 H-NMR spectrum of 1 was identical with that of the esterified cerebroside isolated from human and pig epidermis.

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