Peroxide-induced α-elimination of organic halides from organotellurium (IV) halides

S Uemura, SI Fukuzawa

Index: Uemura, Sakae; Fukuzawa, Shin-ichi Journal of the Chemical Society, Chemical Communications, 1980 , # 21 p. 1033 - 1034

Full Text: HTML

Citation Number: 0

Abstract

Summary Treatment of organotellurium(1v) halides with t-butyl hydroperoxide in 1,4-dioxan, acetic acid, or acetonitrile affords the corresponding organic halides in good to moderate yields presumably as the result of a 1,2-halogen shift. ... THE well established p-elimination giving olefins from organoseleniuni(I1) compounds by oxidationf does not pro- ceed well with organotellurium(I1) compounds.2 In the latter case some alcohols are formed, ...

Related Articles:

The cis chlorination of alkenes using selenium reagents

[Morella, Angelo M.; Ward, A. David Tetrahedron Letters, 1984 , vol. 25, # 11 p. 1197 - 1200]

The Stereochemistry of the Reactions of cis-and trans-2-Chlorocyclohexanol with Thionyl Chloride1

[Stevens; Grummitt Journal of the American Chemical Society, 1952 , vol. 74, p. 4876,4879]

The Stereochemistry of the Reactions of cis-and trans-2-Chlorocyclohexanol with Thionyl Chloride1

[Stevens; Grummitt Journal of the American Chemical Society, 1952 , vol. 74, p. 4876,4879]

More Articles...