End-labeled amino terminated monotelechelic glycopolymers generated by ROMP and Cu (I)-catalyzed azide–alkyne cycloaddition
R Okoth, A Basu
Index: Okoth, Ronald; Basu, Amit Beilstein Journal of Organic Chemistry, 2013 , vol. 9, p. 608 - 612
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Citation Number: 8
Abstract
Abstract Functionalizable monotelechelic polymers are useful materials for chemical biology and materials science. We report here the synthesis of a capping agent that can be used to terminate polymers prepared by ring-opening metathesis polymerization of norbornenes bearing an activated ester. The terminating agent is a cis-butene derivative bearing a Teoc (2-trimethylsilylethyl carbamate) protected primary amine. Post-polymerization ...
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