Chiral Co (II) Metal–Organic Framework in the Heterogeneous Catalytic Oxidation of Alkenes under Aerobic and Anaerobic Conditions

…, G Giambastiani, S Kwon, PC Stair, RQ Snurr…

Index: Tuci, Giulia; Giambastiani, Giuliano; Kwon, Stephanie; Stair, Peter C.; Snurr, Randall Q.; Rossin, Andrea ACS Catalysis, 2014 , vol. 4, # 3 p. 1032 - 1039

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Citation Number: 11

Abstract

The chiral Co (II) MOF [Co (l-RR)(H2O)· H2O]∞[1; l-RR=(R, R)-thiazolidine-2, 4- dicarboxylate] has been exploited in the catalytic oxidation of different alkenes (cyclohexene,(Z)-cyclooctene, 1-octene) using either tert-butyl hydroperoxide (t BuOOH) or molecular oxygen (O2) as oxidants. Different chemoselectivities are observed, both substrate-and oxidant-dependent. A moderate enantioselectivity is also obtained in the ...

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