The Journal of Organic Chemistry

Scope and limitations of aliphatic Friedel-Crafts alkylations. Lewis acid catalyzed addition reactions of alkyl chlorides to carbon-carbon double bonds

H Mayr, W Striepe

Index: Mayr, Herbert; Striepe, Wilhelm Journal of Organic Chemistry, 1983 , vol. 48, # 8 p. 1159 - 1165

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Citation Number: 62

Abstract

Lewis acid catalyzed addition reactions of alkyl halides 1 with unsaturated hydrocarbons 2 have been studied. 1: l addition products 3 are formed if the addends 1 dissociate faster than the corresponding products 3; otherwise, polymerization of 2 takes place. For reaction conditions under which 1 and 3 exist mainly undissociated, solvolysis constants of model compounds can be used to predict the outcome of any such addition reactions if systems ...

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