Tetrahedron: Asymmetry

Resolution of 1-arylalkylamines with 6-(1, 2: 3, 4-di-O-isopropylidene-α-d-galactopyranosyl) hydrogen phthalate

HB Mereyala, L Fatima, P Pola

Index: Mereyala, Hari Babu; Fatima, Liyakat; Pola, Pallavi Tetrahedron Asymmetry, 2004 , vol. 15, # 4 p. 585 - 587

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Citation Number: 12

Abstract

The resolving ability of a new acidic resolving agent, the hydrogen phthalate of 1, 2: 3, 4-di- O-isopropylidene-α-d-galactopyranose, against various 1-arylalkylamines is described. Treatment of with amines obtain diastereomeric salts·(S) in 2-propanol allowing the corresponding (S)-amines be recovered in good yield and 61–89% ee. Recrystallization in dichloromethane/hexane, and regeneration gave the amines in enhanced enantiomeric ...

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