Journal of the American Chemical Society

High Pressure Thermal Alkylation of Monoalkylbenzenes by Butenes1

H Pines, CN Pillai

Index: Pines; Pillai Journal of the American Chemical Society, 1959 , vol. 81, p. 3629,3633

Full Text: HTML

Citation Number: 9

Abstract

The thermal alkylation of monoalkylbenzenes by simple olefins at elevated temperatures and pres- sures has been reported.',' It was found that the selectivity of addition of aralkyl radicals to unsym- metrical olefins paralleled the stability of the inter- mediate free radical formed, viz., 111, 11, I in de- creasing order of stability. It also was found that arene reactivity decreased in the order toluene, ethylbenzene, cumene, indicating the importance of steric factors in ...

Related Articles:

Selenium-assisted reduction of α-and β-diketones with carbon monoxide and water

[Nishiyama, Yutaka; Inoue, Jun; Teranishi, Kazuyo; Moriwaki, Masami; Hamanaka, Sawako Tetrahedron Letters, 1992 , vol. 33, # 42 p. 6347 - 6350]

Cobalt??Catalyzed Cross??Coupling Reactions of Alkyl Halides with Allylic and Benzylic Grignard Reagents and Their Application to Tandem Radical Cyclization/Cross …

[Ohmiya, Hirohisa; Tsuji, Takashi; Yorimitsu, Hideki; Oshima, Koichiro Chemistry - A European Journal, 2004 , vol. 10, # 22 p. 5640 - 5648]

Dendrimers: Solutions For Catalyst Separation and Recycling–A Review†† Dedicated to the memory of Dr. José Antonio Delgado Oyagüe.

[Zweni, Pumza P.; Alper, Howard Advanced Synthesis and Catalysis, 2006 , vol. 348, # 6 p. 725 - 731]

THE PREPARATION OF OPTICALLY ACTIVE HYDRAZINES. III PARA-“ACTIVE-AMYL”-PHENYLHYDRAZINES1

[Glattfeld; Cameron Journal of the American Chemical Society, 1927 , vol. 49, p. 1045]

Nitrene Insertion into a CH Bond at an Asymmetric Carbon Atom with Retention of Optical Activity. Thermally Generated Nitrenes

[Smolinsky,G.; Feuer,B.I. Journal of the American Chemical Society, 1964 , vol. 86, p. 3085 - 3088]

More Articles...