Poly (trimethylsilyl) benzenes: Synthese, sulfonation

P Bourgeois, R Calas, E Jousseaume…

Index: Bourgeois,P.; Calas,R. Journal of Organometallic Chemistry, 1975 , vol. 84, p. 165 - 175

Full Text: HTML

Citation Number: 21

Abstract

Abstract The system Me 3 SiCl/Mg/hexamethylphosphorotriamide (HMPT) reacts with some di-or poly-chlorobenzenes leading directly to the corresponding di-or poly-trimethylsilyl derivatives (yields 70-85%). Reaction of trimethylsilyl chlorosulfonate with these compounds gives in a first step trimethylsilyl arylsulfonic esters, Ph (SiMe 3) SO 3 SiMe 3.

Related Articles:

Kinetics of hydrolysis of aromatic mono-and disulfonyl chlorides

[Sanecki, Przemyslaw; Rokaszewski, Edward Canadian Journal of Chemistry, 1987 , vol. 65, p. 2263 - 2267]

More Articles...