Vibrational product states from reactions of CN− with the hydrogen halides and hydrogen atoms

MM Maricq, MA Smith, C Simpson…

Index: Maricq, M. Matti; Smith, Mark A.; Simpson, C. J. S. M.; Ellison, G. Barney Journal of Chemical Physics, 1981 , vol. 74, # 11 p. 6154 - 6170

Full Text: HTML

Citation Number: 43

Abstract

Infrared chemiluminescence is observed from the C–H stretch manifold ν3 of HCN formed in the gas phase ion–molecule reactions: CN−+ HX→ HCN (v 3)+ X−, with (X= Cl, Br, I), and for CN−+ H→ HCN (v 3)+ e−. Qualitative information is also obtained for excitation in the bending mode. In each case some excitation is observed in the highest level allowed by energy conservation. Comparison with similar studies of the reactions Cl−+ HX shows that ...

Related Articles:

THE OXIDIZING POWER OF CYANATES AND THE FREE ENERGY OF FORMATION OF CYANIDES.

[Lewis, G. N.; Brighton, T. B. Journal of the American Chemical Society, 1918 , vol. 40, p. 482 - 489]

Gas-phase Lewis acid-base interactions. An experimental determination of cyanide binding energies from ion cyclotron resonance and high-pressure mass …

[Larson, J. W.; Szulejko, J. E.; McMahon, T. B. Journal of the American Chemical Society, 1988 , vol. 110, # 23 p. 7604 - 7609]

Gas-phase negative-ion chemistry of methyl isocyanide

[Filley, Jonathan; DePuy, Charles H.; Bierbaum, Veronica M. Journal of the American Chemical Society, 1987 , vol. 109, # 20 p. 5992 - 5995]

Cation-anion combination reactions. 22. Rate and equilibrium constants for reactions of pyronin and thiopyronin with nucleophiles

[Ritchie; Kubisty; Ting Journal of the American Chemical Society, 1983 , vol. 105, # 2 p. 279 - 284]

Gas-phase negative-ion chemistry of methyl isocyanide

[Filley, Jonathan; DePuy, Charles H.; Bierbaum, Veronica M. Journal of the American Chemical Society, 1987 , vol. 109, # 20 p. 5992 - 5995]

More Articles...