Flüssigphasenoxidation von Ethan??1, 2??diol

D Schnurpfeil, G Maurer

Index: Schnurpfeil, D.; Maurer, G. Journal fuer Praktische Chemie/Chemiker-Zeitung, 1994 , vol. 336, # 4 p. 307 - 310

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Abstract

Abstract. The oxidation rate and the kind of oxidation products in the reaction of 1, 2-ethane diol (1) with molecular oxy-gen in liquid phase at 150 C were investigated. 1 has a very low oxidation rate. Cu-, Zn-, Fe-, Co-and Al-acetylacetonates as catalysts increase the reaction rate. The main-products of the investigated reaction are the 1, 3-dioxolan (2), the 2-methyl-1, 3-dioxolan (3) and the 2-mcthylol-l, 3-dioxolan (4). The formation of formic and acetic ...

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