Tetrahedron Letters

Carbonylation of C 7 C 8 cycloalkanes leading to individual tertiary carbonyl-containing compounds

I Akhrem, L Afanas' eva, P Petrovskii, S Vitt…

Index: Akhrem; Afanas'eva; Petrovskii; Vitt; Orlinkov Tetrahedron Letters, 2000 , vol. 41, # 50 p. 9903 - 9907

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Citation Number: 6

Abstract

Carbonylation of cycloheptane, methylcyclohexane, cyclooctane and ethylcyclohexane by CO in the presence of CBr4· 2AlBr3 at− 40° C and 1 atm was performed with good yields and selectivities. Individual esters of tertiary carboxylic acids of the cyclohexane series were the products of these cycloalkane carbonylations.

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