Conjugate addition of allylic groups to α, β-unsaturated carbonyl compounds via (η3-allyl) Fe (CO) 2NO complexes

K Itoh, S Nakanishi, Y Otsuji

Index: Itoh, Keiji; Nakanishi, Saburo; Otsuji, Yoshio Journal of Organometallic Chemistry, 1994 , vol. 473, # 1-2 p. 215 - 224

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Citation Number: 19

Abstract

Abstract (η 3-Allyl) Fe (CO) 2 NO complexes undergo conjugate addition to α, β-unsaturated carbonyl compounds to give the corresponding δ, ϵ-unsaturated carbonyl compounds in good yields. The reaction of (η 3-1-or 2-trimethylsiloxyallyl) Fe (CO) 2 NO complexes with α, β-unsaturated ketones affords 1, 6-or 1, 5-diketones, respectively.(η 3-1-Acetonylallyl) Fe (CO) 2 NO complexes also react with α, β-unsaturated carbonyl compounds to give 1, 8- ...