Journal of Molecular Catalysis A: Chemical

Synthesis of cationic rhodium (I) and iridium (I) carbonyl complexes of tetradentate P (CH 2 CH 2 PPh 2) 3 ligand: An implication of steric inhibition and catalytic …

K Saikia, B Deb, DK Dutta

Index: Saikia, Kokil; Deb, Biswajit; Dutta, Dipak Kumar Journal of Molecular Catalysis A: Chemical, 2014 , vol. 381, p. 188 - 193

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Citation Number: 6

Abstract

Abstract New cationic carbonyl complexes of the type [M (CO) L] Cl (1)[M= Rh (a) and Ir (b); L= P (CH 2 CH 2 PPh 2) 3] have been synthesized and characterized by various spectroscopic techniques including the single crystal X-ray diffraction. Both the complexes crystallize in trigonal bipyramidal symmetry with the metal at the centre. Two strong intermolecular hydrogen bonds are observed in 1a. Despite the high trans effect of the CO ...

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