SnCl4-and TiCl4-catalyzed anomerization of acylated O-and S-glycosides: analysis of factors that lead to higher α: β anomer ratios and reaction rates

W Pilgrim, PV Murphy

Index: Brown, Richard T.; Scheinmann, Feodor; Stachulski, Andrew V. Journal of Chemical Research - Part S, 1997 , # 10 p. 370 - 371

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Citation Number: 42

Abstract

... The Journal of Organic Chemistry. ... paul.v.murphy@nuigalway.ie. ... reactions generated straight line plots with use of the equation(14) where [A] 0 is the initial concentration of the β-substrate, [A] e is the equilibrium concentration, [A] t is the concentration of substrate at a time t, k f is ...