Boron photochemistry. Possible role of bridged intermediates in the photolysis of borate complexes

PJ Grisdale, JLR Williams, ME Glogowski…

Index: Grisdale,P.J. et al. Journal of Organic Chemistry, 1971 , vol. 36, p. 544 - 549

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Citation Number: 47

Abstract

(1) PJ Grisdale, BE Babb, JC Doty, TH Regan, DP Maier, and J. LR Williams, J. Organometal. Chem., 14, 63 (1968). used earlier. Previously we considered two primary photochemical processes:(1) the generation of a phenyl radical (R.) by homolytic fission of a phenyl boron bond in the" ate" complex 1;(2) the generation of a mesityl radical by an analogous process. Path a based on process 1 is shown in Scheme I2 and reveals that in ...

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