Tetrahedron

Regiospecific synthesis of polysubstituted furans from silylated furans: Expedient syntheses of rosefuran

MK Wong, CY Leung, HNC Wong

Index: Wong, Ming Keung; Leung, Chun Yip; Wong, Henry N.C. Tetrahedron, 1997 , vol. 53, # 10 p. 3497 - 3512

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Citation Number: 25

Abstract

By utilizing a sequence of regiospecific lithiation-alkylation, ipso-iodination, boroxine formation, Sonogashira cross-coupling, nickel-catalyzed cross-coupling and Suzuki cross- coupling reactions, several methods have been developed for the syntheses of 2, 3- disubstituted furans, 2, 4-disubstituted furans, 2, 3, 4-trisubstituted furans and 2, 3, 5- trisubstituted furans. Our approach uses as the key theme trimethylsilyl groups as both ...

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