Journal of Organometallic Chemistry

Efficient catalytic aryl amination of bromoarenes using 3-iminophosphine palladium (II) chloride

DC Samblanet, JAR Schmidt

Index: Samblanet, Danielle C.; Schmidt, Joseph A. R. Journal of Organometallic Chemistry, 2012 , vol. 720, p. 7 - 18,12

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Citation Number: 4

Abstract

While pursuing the development of new hydroamination catalysts, a 3-iminophosphine palladium (II) chloride complex [(3IP) PdCl2] was synthesized that has subsequently proven to be an effective precatalyst for the aryl amination of bromoarenes. This (3IP) PdCl2 complex has been utilized in the catalytic aryl amination of both bromobenzene and bromopyridine derivatives, specifically yielding excellent activity in coupling reactions ...

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