A Practical and Efficient Synthesis of Fluorinated Pyrethroids. cis-3-(2-Chloro-3, 3, 3-trifluoro-1-propenyl)-2, 2-dimethylcyclopropanecarboxylates.
M Nishida, T Fuchikami, K Kondo
Index: Nishida, Mayumi; Fuchikami, Takamasa; Kondo, Kiyosi Chemistry Letters, 1994 , # 4 p. 703 - 706
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Abstract
A practical and efficient route to fluorinated pyrethroids has been developed which involves the selective formation of the cis cyclopropane ring using intramolecular alkylation of the haloaldehyde and a novel transformation of the aldehydes to the corresponding esters via the cyanohydrins.
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