Iodine??Catalyzed Regioselective Sulfenylation of Indoles with Sodium Sulfinates
F Xiao, H Xie, S Liu, GJ Deng
Index: Xiao, Fuhong; Xie, Hao; Liu, Saiwen; Deng, Guo-Jun Advanced Synthesis and Catalysis, 2014 , vol. 356, # 2-3 p. 364 - 368
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Citation Number: 82
Abstract
Abstract: An iodine-catalyzed sulfenylation of free indoles with sodium sulfinates is described. The reaction selectively afforded 3-arylthioindoles in good to high yields in anisole under metal-free conditions. Functional groups such as halogens were well tolerated under the optimized reaction conditions. Keywords: indoles; iodine; sodium sulfinates; sul-ACHTUNGTRENNUNGfenylation; transition metal-free conditions
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