The Journal of organic chemistry

Syntheses and synthetic applications of stannylated allylic alcohols

U Kazmaier, S Lucas, M Klein

Index: Kazmaier, Uli; Lucas, Simon; Klein, Manuela Journal of Organic Chemistry, 2006 , vol. 71, # 6 p. 2429 - 2433

Full Text: HTML

Citation Number: 44

Abstract

Allenyl carbinols undergo regioselective hydrostannation in the presence of MoBl3, a catalyst originally developed for the hydrostannation of alkynes, giving rise to allyl stannanes. These allyl stannanes can easily be converted into useful synthetic building blocks such as allyl iodides or vinyl epoxides.

Related Articles:

Concerning Aromatic Acetylenic Carbinols

[Rutan; May Journal of the American Chemical Society, 1947 , vol. 69, p. 2017]

662. The reaction of 3-bromo-4-chromanone and of 4-chromone with diethylamine and other bases

[Lockhart,I.M.; Tanner,E.M. Journal of the Chemical Society, 1965 , p. 3610 - 3613]

Stereoselective alkynylation of chiral benzaldehyde chromium tricarbonyl complexes. Synthesis of optically active alkynyl alcohols

[Baldoli, Clara; Del Buttero, Paola; Licandro, Emanuela; Maiorana, Stefano; Papagni, Antonio; Torchio, Maurizio Tetrahedron Letters, 1993 , vol. 34, # 49 p. 7943 - 7946]

Stereoselective alkynylation of chiral benzaldehyde chromium tricarbonyl complexes. Synthesis of optically active alkynyl alcohols

[Baldoli, Clara; Del Buttero, Paola; Licandro, Emanuela; Maiorana, Stefano; Papagni, Antonio; Torchio, Maurizio Tetrahedron Letters, 1993 , vol. 34, # 49 p. 7943 - 7946]

More Articles...