Oligomerisation of methyloxirane initiated by (C 6 H 5) 3 C+ AsF 6-,(C 6 H 5) 3 C+ SbCl 6-and SbCl 5

J Vohlídal, M Pacovská, J Dvořák

Index: Vohlidal, Jiri; Pacovska, Marta; Dvorak, Jiri Collection of Czechoslovak Chemical Communications, 1982 , vol. 47, # 9 p. 2351 - 2362

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Citation Number: 4

Abstract

Abstract Reactions of methyloxirane with the title compounds lead to the formation of a mixture of cyclic and linear oligomers with average polymerisation degree ranging from 5 to 10. The oligomers are formed by combination of back-bitting reaction with re-initiation of the transiently desactivated reaction centers followed by monomer transfer. The important role which these reactions play in the overall oligomerisation of methyloxirane is due to the fact ...