Fluorinated 3-diethylaminopropenoates and their reactions

J Svoboda, O Paleta, F Liška…

Index: Svoboda, Jiri; Paleta, Oldrich; Liska, Frantisek; Dedek, Vaclav Collection of Czechoslovak Chemical Communications, 1981 , vol. 46, # 6 p. 1389 - 1396

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Citation Number: 7

Abstract

Abstract The reaction of diethylamine with methyl trifluoropropenoate (I), methyl 2-chloro-3, 3- difluoropropenoate (II), methyl 3, 3-difluoropropenoate III) and methyl 3-chloro-2, 3- difluoropropenoate (IV) affords halogenated 3-diethylaminopropenoates V-VII via the vinylic substitution of fluorine or chlorine atoms. When hydrolyzed the latter give methyl N, N- diethylcarbamoylacetates X-XII. On addition of 1-butanol and 2, 2, 3, 3-tetrafluoropropanol ...

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