Electron affinity of chlorine dioxide

LM Babcock, T Pentecost…

Index: Babcock, L. M.; Pentecost, T.; Koppenol, W. H. Journal of Physical Chemistry, 1989 , vol. 93, # 25 p. 8126 - 8127

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Citation Number: 15

Abstract

Recently, the reduction potential of the formate radical, COz'was calculated to be-1.8 V from the electron affinity of carbon dioxide and a Gibbs hydration energy estimated to be similar to those of other bent triatomic anions, namely, 03'-, NOT, and S02*-. l The assumption that these anions have similar Gibbs hydration energies can be tested by determining the electron affinity of the chlorine dioxide radical and calculating the Gibbs hydration energy ...

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