The Journal of organic chemistry

Hydrogen-free homogeneous catalytic reduction of olefins in aqueous solutions

C Gaviglio, F Doctorovich

Index: Gaviglio, Carina; Doctorovich, Fabio Journal of Organic Chemistry, 2008 , vol. 73, # 14 p. 5379 - 5384

Full Text: HTML

Citation Number: 9

Abstract

Herein we report a study involving the homogeneous catalytic reduction of unsaturated substrates in aqueous solutions or water− organic solvent mixtures. The reduction of olefins has been carried out in the presence of catalytic amounts of [Fe (CN) 5NH3] 3-and excess of NH2OH, which under mild reaction conditions can be used to reduce carbon− carbon unsaturations without affecting carbonyl functionalities and aromatic rings. To explore the ...

Related Articles:

Stereospecificity of the reaction catalyzed by enoyl-CoA hydratase

[Wu, Wen-Jin; Feng, Yuguo; He, Xiang; Hofstein, Hilary A.; Raleigh, Daniel P.; Tonge, Peter J. Journal of the American Chemical Society, 2000 , vol. 122, # 17 p. 3987 - 3994]

The detection of PHIP effects allows new insights into the mechanism of olefin isomerisation during catalytic hydrogenation

[Viale, Alessandra; Santelia, Daniela; Napolitano, Roberta; Gobetto, Roberto; Dastru, Walter; Aime, Silvio European Journal of Inorganic Chemistry, 2008 , # 28 p. 4348 - 4351]

Modified photobehavior of carboxylic acid derivatives induced by protonation

[Amat, Ana M.; Asensio, Gregorio; Castello, Maria J.; Miranda, Miguel A.; Simon-Fuentes, Antonio Tetrahedron, 1987 , vol. 43, # 5 p. 905 - 910]

Novel syn intramolecular pathway in base-catalyzed 1, 2-elimination reactions of β-acetoxy esters

[Mohrig, Jerry R.; Carlson, Hans K.; Coughlin, Jane M.; Hofmeister, Gretchen E.; McMartin, Lea A.; Rowley, Elizabeth G.; Trimmer, Elizabeth E.; Wild, Andrew J.; Schultz, Steve C. Journal of Organic Chemistry, 2007 , vol. 72, # 3 p. 793 - 798]

Tungsten (0) alkylidene complexes stabilized as pyridinium ylides: new aspects of their synthesis and reactivity

[Rudler, Henri; Durand-Reville, Thomas Journal of Organometallic Chemistry, 2001 , vol. 617, # 1 p. 571 - 587]

More Articles...