Anodic oxidation. Part IX. Electrolysis of ethyl sodiomethylacetoacetate

R Brettle, JG Parkin, D Seddon

Index: Brettle,R. et al. Journal of the Chemical Society [Section] C: Organic, 1970 , p. 1317 - 1320

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Citation Number: 6

Abstract

The electrolysis of ethyl sodiomethylacetoacetate in NN-dimethylacetamide at a platinum anode gives diethyl α, α′-diacetyl-α, α′-dimethylsuccinate, 4, 5-diethoxycarbonyl-3, 4, 5- trimethylcyclopent-2-enone and 4-ethoxycarbonyl-3, 4-dimethylcyclohex-2-enone. Degradation of these products with aqueous ethanolic alkali gives a mixture of dimethylcyclohexenones and trimethylcyclopentenones; the synthesis of 2, 3, 4- ...

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