Factors controlling regioselectivity in the reduction of polynitroaromatics in aqueous solution

SE Barrows, CJ Cramer, DG Truhlar…

Index: Barrows, Susan E.; Cramer, Christopher J.; Truhlar, Donald G.; Elovitz, Michael S.; Weber, Eric J. Environmental Science and Technology, 1996 , vol. 30, # 10 p. 3028 - 3038

Full Text: HTML

Citation Number: 78

Abstract

Regioselectivities in the bisulfide reduction of 10 polynitroaromatics (PNAs) to monoamine products have been determined; four of these compounds have also been reduced by anoxic sediments in heterogeneous aqueous solution, and the same regioselectivities are observed. Analyses of Austin Model 1-Solvation Model 2 electrostatic potential surfaces for the radical anions of these polynitroaromatic compounds provides a reliable method of ...

Related Articles:

Regioselective reduction of substituted dinitroarenes using baker's yeast

[Tetrahedron Letters, , vol. 35, # 42 p. 7867 - 7870]

Partial reduction of dinitroarenes to nitroanilines with hydrazine hydrate.

[Bulletin of the Chemical Society of Japan, , vol. 56, # 10 p. 3159 - 3164]

New Nitronate σ Complexes and the Mechanism of Nucleophilic Aromatic Photosubstitution Para to a Nitro Group

[Organic Letters, , vol. 8, # 7 p. 1451 - 1454]

The Search for Biochemical Photoprobes. III. The Photoreactions of 4-Nitroveratrole and 2-Fluoro-4-nitroanisole with Bovine Pancreatic Ribonuclease A and with …

[Tetrahedron, , vol. 49, # 6 p. 1297 - 1306]

Journal of the American Chemical Society, Vol. 63, 1941: The concentration of" folic acid" by Herschel K. Mitchell, Esmond E. Snell, and Roger J. Williams.

[Journal of the American Chemical Society, , vol. 63, p. 609]

More Articles...