Nitration Studies. XII. Nitrohalogenation of Negatively Substituted Olefins with Mixtures of Dinitrogen Tetroxide and Halogens

GB BACHMAN, TEDJ LOGAN, KR HILL…

Index: Bachman,G.B. et al. Journal of Organic Chemistry, 1960 , vol. 25, p. 1312 - 1322

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Citation Number: 14

Abstract

Mixtures of dinitrogen tetroxide and halogens have been shown to react mith olefins to produce compounds with a halogen atom on one carbon atom and a nitrogen-containing group on the other carbon atom of the original double bond. The nitrogen-containing group is-OXO2 when the olefin is ethylene itself or ethylene substituted with electron-supplying groups such as alkyl or acetoxy. It is--NO2 when the olefin is ethylene substituted with ...