Reactions of perfluoronitriles. I. Interactions with aniline

KJL Paciorek, JH Nakahara, RH Kratzer

Index: Paciorek, K. J. L.; Nakahara, J. H.; Kratzer, R. H. Journal of Fluorine Chemistry, 1985 , vol. 30, p. 241 - 250

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Citation Number: 7

Abstract

Abstract Perfluoro-n-octanonitrile was found to react with aniline both in the absence and presence of solvents. A spectrum of products was formed including tris (perfluoro-n-heptyl)-s- triazine, N-phenyl-perfluoro-n-octylamidine, and N′-(perfluoro-n-octylimidoyl)-N-phenyl- perfluoro-n-octylamidine, as well as the diphenyl analogues of the last two compounds. The reaction mechanisms, infrared and mass spectra are discussed