TRANSFORMATION OF ORGANOPHOSPHORUS S-TRIFLUOROMETHYLTHIOATES RR'P (O) SCFs INTO FLUORIDATES RR'P (0) F3 STEREOCHEMICAL …

A Łopusiński

Index: Lopusinski, Andrezej Phosphorus, Sulfur and Silicon and the Related Elements, 1990 , vol. 47, p. 383 - 390

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Abstract

Abstract The stereochemical course of the thermal or by nucleophiles catalyzed extrusion reaction of thiocarbonyl fluoride from Two diastereoisomeric (6) and optically active (10) organophosphorus S-trifluoromethylthioates has been investigated. To explain the observed retention of configuration at phosphorus in fluoridates 7 formed in the thermal reactions, a four center transition state for such reactions has been proposed. The lack of the ...

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