2, 2, 2-Trifluoroethylamine and 2, 2, 2-Trifluorodiazoethane

H Gilman, RG Jones

Index: Gilman; Jones Journal of the American Chemical Society, 1943 , vol. 65, p. 1459

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Citation Number: 127

Abstract

Reactions [I],[11] and [111] were carried out essentially as described by Swarts." However, a decided improvement in the yield of trifluoroacetamide was realized by treating ethyl trifluoroacetate with dry ammonia rather than with ammonium hydroxide. The catalytic hydrogenation [IV] was effected at a temperature of 50 to GO", and hydrogen pressures above 1000 lb./sq. in., using a liberal quantity of Adams platinum catalyst. No secondary ...