The Journal of Organic Chemistry

Regioselective hydroesterification and hydrocarboxylation of 3, 3, 3-trifluoropropene and pentafluorostyrene catalyzed by phosphine-palladium complex

T Fuchikami, K Ohishi, I Ojima

Index: Fuchikami, Takamasa; Ohishi, Katsuyuki; Ojima, Iwao Journal of Organic Chemistry, 1983 , vol. 48, # 21 p. 3803 - 3807

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Citation Number: 68

Abstract

The hydroesterification and hydrocarboxylation of 3, 3, 3-trifluoropropene (TFP) and pentafluorostyrene (PFS) catalyzed by phosphine-palladium complexes were studied. It was found that the efficiency and the product distribution of the reaction depended markedly on the nature of nucleophile, Le., water or alcohol, the structures of olefin and phosphine ligand, and other reaction variables such as solvent, temperature, and carbon monoxide ...