Tetrahedron letters

Metal template ortho-acylation of phenols; A new general approach to anthracyclinones

G Sartori, G Casnati, F Bigi, P Robles

Index: Sartori, Giovanni; Casnati, Giuseppe; Bigi, Franca; Robles, Pasquale Tetrahedron Letters, 1987 , vol. 28, # 14 p. 1533 - 1536

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Citation Number: 32

Abstract

... 3; F. Bigi, G. Casiraghi, G. Casnati, G. Sartori; J. Chem. Soc. Perkin Trans. I (1984), p. 2655 and unpublished data from our laboratories. 4; Compound 1 was prepared by reaction of C 2 H 5 MgBr with o-tert-butylphenol in dry ether followed by stripping of the ether and exchange with dry toluene. o-tert-butyl phenol was chosen because of the solubility of its bromomagnesium salt in toluene. ...

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