J. Chem. Soc., Chem. Commun.

Unprecedented reductive dealkoxylation of aryl alkyl ethers and intramolecular C–C coupling of 2, 2′-dialkoxystilbenes with low valent titanium: one-pot synthesis of …

A Banerji, SK Nayak

Index: Banerji, Asoke; Nayak, Sandip, K. Journal of the Chemical Society, Chemical Communications, 1991 , # 20 p. 1432 - 1434

Full Text: HTML

Citation Number: 15

Abstract

Facile dealkoxylation of aryl alkyl ethers has been carried out using TiCIrLi-THF (tetrahydrofuran); a novel one-pot synthesis of phenanthrenes from ortho-alkoxyaromatic aldehydedketones is described. ... In continuation of our work'-3 on the use of low valent titanium in organic synthesis, we report for the first time an unusual reductive dealkoxylation of aryl alkyl ethers and intramolecular CC coupling of 2,2'-dialkoxystilbenes leading to a one-pot synthesis of ...

Related Articles:

Influence of external ligands and auxiliaries on the reactivity of low-valent titanium in McMurry reaction: Selectivity and mechanistic profile

[Balu; Nayak; Banerji Journal of the American Chemical Society, 1996 , vol. 118, # 25 p. 5932 - 5937]

A facile two-step synthesis of 2-arylbenzofurans based on the selective cross McMurry couplings

[Duan, Xin-Fang; Zeng, Jing; Lue, Jia-Wei; Zhang, Zhan-Bin Journal of Organic Chemistry, 2006 , vol. 71, # 26 p. 9873 - 9876]

Cyclopropyl Analogs of Hexestrol and Diethylstilbestrol1, 2

[Bennett,J.G.; Bunce,S.C. Journal of Organic Chemistry, 1960 , vol. 25, p. 73 - 79]

More Articles...