Kinetics of insertion reactions of dimethylsilylene

IMT Davidson, FT Lawrence, NA Ostah

Index: Davidson, Iain M. T.; Lawrence, F. Timothy; Ostah, Naaman A. Journal of the Chemical Society, Chemical Communications, 1980 , # 18 p. 859 - 860

Full Text: HTML

Citation Number: 0

Abstract

Dimethylsilylene, generated by photolysis of dodecamethylcyclohexasilane, inserts into the silicon–hydrogen bond in trimethylsilane and pentamethyldisilane with approximately zero activation energy, while insertion into hydrogen chloride requires an activation energy of 28 kJ mol; the results for silicon–hydrogen i

Related Articles:

Photolysis of permethylated linear polysilanes

[Ishikawa,M. et al. Journal of Organometallic Chemistry, 1972 , vol. 42, p. 333 - 338]

Thermolysis of pentamethyldisilane and 1 H-heptamethyltrisilane

[Sakurai,H. et al. Journal of the Chemical Society [Section] D: Chemical Communications, 1969 , p. 4 - 5]

Coordinatively Unsaturated Ru (II) Species Ru (xantsil)(CO): A New Active catalyst for Oligomerization/Deoligomerization of HSiMe2SiMe3 [xantsil=(9, 9- …

[Minglana, Jim Josephus G.; Okazaki, Masaaki; Tobita, Hiromi; Ogino, Hiroshi Chemistry Letters, 2002 , # 3 p. 406 - 407]

More Articles...