1, 3, 4??oxadiazolin??2??ones from carbo??t??butoxyhydrazones

HE Baumgarten, DR Hwang…

Index: Baumgarten, Henry E.; Hwang, Deng-Ruey; Rao, T. N. Journal of Heterocyclic Chemistry, 1986 , vol. 23, p. 945 - 949

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Citation Number: 14

Abstract

Abstract 5-Substituted-1, 3, 4-oxadiazolin-2-ones 2 were synthesized by the oxidation of carbo-t-butoxyhydrazones 1 of aromatic aldehydes with lead tetraacetate or, preferably, iodosobenzene diacetate. In some instances 5-acetoxy-1, 3, 4-oxadiazoles 3 were obtained along with 2. The oxidation of carboethoxyhydrazones 4 gave 2-ethoxy-1, 3, 4-oxadiazoles 5.

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