Advanced Synthesis & Catalysis

A Tripodal Peptidic Titanium Phosphonate as a Homochiral Porous Solid Medium for the Heterogeneous Enantioselective Hydration of Epoxides

A Milo, R Neumann

Index: Milo, Anat; Neumann, Ronny Advanced Synthesis and Catalysis, 2010 , vol. 352, # 13 p. 2159 - 2165

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Citation Number: 11

Abstract

Abstract A porous, homochiral titanium-phosphonate material based on a tripodal peptide scaffold was used as a heterogeneous reaction medium for the enantioselective hydration (> 99%) of styrene oxide. This titanium-phosphonate material, which was shown to contain confined chiral spaces, was prepared by polymerization of L-leucine onto a tris (2- aminoethyl) amine initiator, followed by capping with phosphonate groups and completed ...

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