Russian journal of general chemistry

Chemistry of dioxacyclanes: XI. Synthesis and properties of unsaturated derivatives of 1, 3-dioxolanes

AK Kerimov

Index: Kerimov Russian Journal of General Chemistry, 2004 , vol. 74, # 2 p. 256 - 260

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Citation Number: 2

Abstract

Abstract 1'3-Dioxolanes were synthesized by reactions of 3-cyclohexenecarboxaldehyde, 5- norbornene-2-endo-carboxaldehyde with 1, 2-ethanedithiol and 3-(2-propenyloxy)-and 3- propoxy-1, 2-propanediols, aswell as of propionaldehyde, benzaldehyde, and trichloroacetaldehyde with the latter two thiols. Dichlorocarbene addition, bromination, and epoxidation of the ring C= C were accomplished, and activity of the resulting products as ...