Macromolecules

Synthesis of water-soluble, ester-terminated dendrons and dendrimers containing internal PEG linkages

…, KK Kotta, A Mishra, CN Moorefield

Index: Newkome, George R.; Kotta, Kishore K.; Mishra, Amaresh; Moorefield, Charles N. Macromolecules, 2004 , vol. 37, # 22 p. 8262 - 8268

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Citation Number: 22

Abstract

Dendrimers up to three generations, possessing internal PEG units within the branching framework, were synthesized by a convergent approach via the reaction of amine-based dendrons 6, 9, and 11 with 6, 6-bis (4-chlorocarbonyl-2-oxabutyl)-4, 8-dioxaundecane-1, 11- dicarbonyl chloride. These new constructs were fully characterized, shown to exhibit good solubilities in organic as well as aqueous solvents, and demonstrated to solubilize lithium ...

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