Selective Rhodium (III)??Catalyzed Cross??Dehydrogenative Coupling of Furan and Thiophene Derivatives

N Kuhl, MN Hopkinson, F Glorius

Index: Kuhl, Nadine; Hopkinson, Matthew N.; Glorius, Frank Angewandte Chemie - International Edition, 2012 , vol. 51, # 33 p. 8230 - 8234

Full Text: HTML

Citation Number: 91

Abstract

The cross-dehydrogenative coupling (CDC) of two unfunctionalized arenes is one of the most attractive transformations to build up the ubiquitous biaryl motif.[1, 2] In comparison to established cross-coupling reactions between aryl halides and organometallic reagents,[3] CDC is considered a more efficient and environmentally friendly approach since it circumvents the often tedious and wasteful prefunctionalization of starting materials. ...

Related Articles:

A High Yielding Synthesis 3-Arylthiophenes Under Phase-Transfer Conditions

[Sastry, C. V. Reddy; Marwah, A. K.; Marwah, Padma; Rao, G. Shankar; Shridhar, D. R. Synthesis, 1987 , # 11 p. 1024 - 1025]

Efficient coupling of heteroaryl halides with arylboronic acids in the presence of a palladium–tetraphosphine catalyst

[Feuerstein, Marie; Doucet, Henri; Santelli, Maurice Journal of Organometallic Chemistry, 2003 , vol. 687, # 2 p. 327 - 336]

A simple catalytic system based on PdCl 2 (CH 3 CN) 2 in water for cross-coupling reactions using diazonium salts

[El Bakouri, Ouissam; Fernandez, Marti; Brun, Sandra; Pla-Quintana, Anna; Roglans, Anna Tetrahedron, 2013 , vol. 69, # 46 p. 9761 - 9765]

More Articles...