A New, Non??Iterative Asymmetric Synthesis of Long??Chain 1, 3??Polyols
ME Schwenter, P Vogel
Index: Schwenter, Marc-Etienne; Vogel, Pierre Chemistry - A European Journal, 2000 , vol. 6, # 22 p. 4091 - 4103
Full Text: HTML
Citation Number: 36
Abstract
Abstract A new approach to the asymmetric synthesis of pentadeca-1, 3, 5, 7, 9, 11, 13, 15- octols and their derivatives is presented. It is based on the Sharpless asymmetric dihydroxylation (AD) of 4, 4′-methylene [(1R, 1′ S, 6R, 6′ S)-6-acetoxycyclohept-3-en-1- yl] bis (4-methoxybenzoate)(9), derived from a double [3+ 4] cycloaddition of the 1, 1, 3- trichloro-2-oxyallyl cation with 2, 2′-methylenedifuran (1). The diol (−)-10, obtained in ...
Related Articles:
[Gilman; Wright Journal of the American Chemical Society, 1933 , vol. 55, p. 3302,3310]
[Gilman; Wright Journal of the American Chemical Society, 1933 , vol. 55, p. 3302,3310]
[Tanaka, Sanae; Tomokuni, Hidehiko Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 4 p. 991 - 994]
[Musau, Richard M.; Whiting, Andrew Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 19 p. 2881 - 2888]
[Haas, Wilhelm; Knipp, Bernd; Sicken, Martin; Lex, Johann; Vogel, Emanuel Angewandte Chemie, 1988 , vol. 100, # 3 p. 448 - 450]