Mononuclear and Mixed-Valence Trinuclear Manganese Complexes Containing Tripodal Tetradentate Ligands. Phenolato, Carboxylato, and Alkoxo Bridges.

M Hirotsu, M Kojima, Y Yoshikawa

Index: Hirotsu, Masakazu; Kojima, Masaaki; Yoshikawa, Yuzo Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 3 p. 649 - 657

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Citation Number: 29

Abstract

Manganese complexes containing tripodal tetradentate ligands with an N 2 O 2 donor set (H 2 L 1: N, N-bis (2-hydroxybenzyl)-N′, N′-dimethylethylenediamine, H 2 L 2: N-(3, 5-di-t- butyl-2-hydroxybenzyl)-N-(2-hydroxybenzyl)-N′, N′-dimethylethylenediamine, H 2 L 3: N, N-bis (3, 5-di-t-butyl-2-hydroxybenzyl)-N′, N′-dimethylethylenediamine) have been prepared. The mononuclear and trinuclear complexes with the additional carboxylate ...