Chemistry Letters

Novel method for the preparation of triethylsilyl peroxides from olefins by the reaction with molecular oxygen and triethylsilane catalyzed by bis (1, 3-diketonato) cobalt …

S Isayama, T Mukaiyama

Index: Isayama, Shigeru; Mukaiyama, Teruaki Chemistry Letters, 1989 , p. 573 - 576

Full Text: HTML

Citation Number: 48

Abstract

In the presence of a catalytic amount of bis (1, 3-diketonato) cobalt (II), various olefins react with molecular oxygen and triethylsilane at room temperature to give the corresponding triethylsilyl peroxides in high yields under neutral conditions. The reaction provides a new method for the preparation of various peroxides directly from olefins.