Tetrahedron letters

Mn (III)-Mediated electrochemical C, C-bond formation: radical addition of polyhalomethanes to olefins

K Nohair, I Lachaise, JP Paugam, JY Nédélec

Index: Nohair, Khaddouj; Lachaise, Isabelle; Paugam, Jean-Paul; Nedelec, Jean-Yves Tetrahedron Letters, 1992 , vol. 33, # 2 p. 213 - 216

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Citation Number: 17

Abstract

Abstract Free-radical chain addition of various polyhalomethanes onto olefins can be easily initiated by electrochemically in situ generated manganic salt used in catalytic amount associated with an equimolar amount of a Mn (III)-oxidizable compound like methyl cyano-or aceto-acetate.