Mercury (II)-mediated cyclisation of hydroperoxyalkylcyclopropanes: a new route to cyclic peroxides

AJ Bloodworth, D Korkodilos

Index: Bloodworth, A. J.; Korkodilos, Despoina Tetrahedron Letters, 1991 , vol. 32, # 47 p. 6953 - 6956

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Citation Number: 13

Abstract

Abstract Aldehydes, RCHO (R= Me, Et, i Pr, and cC 6 H 11), have been converted via alkylation, cyclopropanation, oxidation, condensation with p-tosylhydrazine, reduction and perhydrolysis into 2-hydroperoxyalkylcyclopropanes, RCH (OOH) CH 2 cC 3 H 5, and