Tetrahedron

A convenient cross-metathesis approach to trisporins

C López-Sánchez, C Hernández-Cervantes, A Rosales…

Index: Lopez-Sanchez, Cristobal; Hernandez-Cervantes, Carmen; Rosales, Antonio; Alvarez-Corral, Miriam; Munoz-Dorado, Manuel; Rodriguez-Garcia, Ignacio Tetrahedron, 2009 , vol. 65, # 46 p. 9542 - 9549

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Citation Number: 9

Abstract

Three series of trisporins have been prepared using a strategy in which a cross-metathesis is the key step. This reaction has proved to be highly regioselective, allowing the combination of α-or β-ionone derivatives having a 1, 1-disustituted olefin with trisubstituted alkenes. The stereochemistry of the newly formed olefins has been established by spectroscopic means.

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