Silylene transfer to carbonyl compounds and subsequent Ireland-Claisen rearrangements to control formation of quaternary carbon stereocenters

SA Calad, KA Woerpel

Index: Journal of the American Chemical Society, , vol. 127, # 7 p. 2046 - 2047

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Citation Number: 48

Abstract

... Journal of Organic Chemistry (1996), 61 ... (American Chemical Society). Silanediyl ((2-(Me2NCH2)C6H4)2Si: or Ar2Si:, 2) (generated by thermolysis of the corresponding cyclotrisilane) reacts with benzophenone, tetracyclone, and fluorenone to yield products I (X = ...