The Products of the Thermal Decomposition of Bis-δ-phenylvaleryl Peroxide in Carbon Tetrachloride and in Benzene

DF Detar, C Weis

Index: DeTar; Weis Journal of the American Chemical Society, 1956 , vol. 78, p. 4296,4300

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Citation Number: 28

Abstract

The thermal decomposition of bis-6-pheuylvaleryl peroxide has been studied in solution in carbon tetrachloride and in Ixnzene. By use of dilute solutions (4-16 mmolar) and of an aliphatic type of peroxide, complicating induced decomposition reactions have been minimized. The expected 8-phenylbutyl radical intermediate is structurally capable of cyclizing to give tetraliii; tetralin\ vas formed in 30% yield in benzene but was absent from ...