Isolation and characterization of acetyl hypofluorite

EH Appelman, MH Mendelsohn…

Index: Appelman, Evan H.; Mendelsohn, Marshall H.; Kim, Hyunyong Journal of the American Chemical Society, 1985 , vol. 107, # 23 p. 6515 - 6518

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Citation Number: 25

Abstract

Abstract: Acetyl hypofluorite, H3CC (0) OF, has been prepared by passage of diluted fluorine through solid KOAc. 2HOAc and isolated by trapping at-78" C. It is a slightly yellow liquid (mp ca.-96" C) with a vapor pressure of about 4 torr at-40" C. Vapor-pressure measurements between-64 and-20" C lead to an enthalpy of vaporization of 35.6 f 2.4 kJ/mol and an extrapolated normal boiling point of 53 f 6" C. At-78" C, in 1: l (v/v) CCI4: CDCl3, its I9F ...

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