Russian Journal of General Chemistry

Oxidation of 2-acetoxytoluene with ozone in acetic anhydride

AG Galstyan

Index: Galstyan Russian Journal of General Chemistry, 2008 , vol. 78, # 9 p. 1690 - 1694

Full Text: HTML

Citation Number: 0

Abstract

Abstract Kinetics and mechanism of the reaction of ozone with 2-acetoxytoluene in acetic anhydride in the presence of sulfuric acid were studied. It was shown that the prevailing reaction route under these conditions is ozonolysis (89%), and the selectivity of the oxidation of the substrate by the methyl group is no higher 9%. However, in the presence of manganese (II) sulfate as a catalyst, the selectivity increases to 76%. The major reaction ...

Related Articles:

Preparation, characterization and use of poly (4-vinylpyridinium) perchlorate as a new, efficient, and versatile solid phase catalyst for acetylation of alcohols, phenols …

[Khaligh, Nader Ghaffari Journal of Molecular Catalysis A: Chemical, 2012 , vol. 363-364, p. 90 - 100]

Zeolite HSZ-360 as a new reusable catalyst for the direct acetylation of alcohols and phenols under solventless conditions

[Ballini, Roberto; Bosica, Giovanna; Carloni, Silvia; Ciaralli, Lara; Maggi, Raimondo; Sartori, Giovanni Tetrahedron Letters, 1998 , vol. 39, # 33 p. 6049 - 6052]

H3PW12O40@[bmim][FeCl4]: A green catalytic system for alkoxymethylation of alcohols and their one-pot interconversion to acetates and TMS-ethers

[Mohammadpoor-Baltork; Moghadam; Tangestaninejad; Mirkhani; Khosropour; Mirjafari Journal of the Iranian Chemical Society, 2011 , vol. 8, # 2 p. 513 - 524]

Lewis acid catalyzed acylation reactions: scope and limitations

[Chandra, Kusum L; Saravanan; Singh, Rajesh K; Singh, Vinod K Tetrahedron, 2002 , vol. 58, # 7 p. 1369 - 1374]

Study of reaction of isomeric acetoxytoluenes with ozone in liquid phase in the presence of manganese bromide catalyst

[Galstyan; Sedykh Russian Journal of General Chemistry, 2010 , vol. 80, # 5 p. 948 - 952]

More Articles...